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21.
We investigated the resistive switching characteristics of a polystyrene:ZnO–graphene quantum dots system and its potential application in a one diode-one resistor architecture of an organic memory cell. The log–log I–V plot and the temperature-variable I–V measurements revealed that the switching mechanism in a low-current state is closely related to thermally activated transport. The turn-on process was induced by a space-charge-limited current mechanism resulted from the ZnO–graphene quantum dots acting as charge trap sites, and charge transfer through filamentary path. The memory device with a diode presented a ∼103 ION/IOFF ratio, stable endurance cycles (102 cycles) and retention times (104 s), and uniform cell-to-cell switching. The one diode-one resistor architecture can effectively reduce cross-talk issue and realize a cross bar array as large as ∼3 kbit in the readout margin estimation. Furthermore, a specific word was encoded using the standard ASCII character code. 相似文献
22.
Sason Shaik Miri Karni David Danovich Yitzhak Apeloig 《Israel journal of chemistry》2015,55(11-12):1167-1176
We tell the story of the Lise Meitner-Minerva Center, its establishment and activities, its members and their scientific activity, and its instrumental role in weaving intense relationships with the theoretical community in Germany, and in amalgamating the Israeli community of computational quantum chemistry into a national center that enjoys a high international reputation. 相似文献
23.
通过微波法直接在水溶液中制备了碳量子点(CDs),并研究了其荧光性质。重点讨论了铁(Ⅲ)对该量子点的荧光猝灭效应,并将其应用于铁(Ⅲ)的测定。实验表明,在pH值为6.40的磷酸氢二钠-柠檬酸缓冲溶液中,控制CDs浓度为6.24×10-5 mol/L(以碳计),在常温下反应10min时,于激发波长335nm,发射波长为450nm处进行测定,铁(Ⅲ)浓度与体系荧光猝灭程度(ΔF)呈良好的线性关系,线性回归方程为ΔF=69.816 c+4.813 6,相关系数为0.9987,线性范围为0.004~0.15mmol/L。方法检出限为2.4×10-4 mmol/L。将体系应用于水样中铁(Ⅲ)的测定,结果与原子吸收光谱法(AAS)基本一致,相对标准偏差(RSD,n=6)在1.5%~2.1%之间,加标回收率为92%~104%。 相似文献
24.
Within the framework of the effective-mass approximation and the dipole approximation, considering the three-dimensional confinement of the electron and hole and the strong built-in electric field(BEF) in strained wurtzite Zn O/Mg0:25Zn0:75O quantum dots(QDs), the optical properties of ionized donor-bound excitons(D+, X)are investigated theoretically using a variational method. The computations are performed in the case of finite band offset. Numerical results indicate that the optical properties of(D+, X) complexes sensitively depend on the donor position, the QD size and the BEF. The binding energy of(D+, X) complexes is larger when the donor is located in the vicinity of the left interface of the QDs, and it decreases with increasing QD size. The oscillator strength reduces with an increase in the dot height and increases with an increase in the dot radius. Furthermore, when the QD size decreases, the absorption peak intensity shows a marked increment, and the absorption coefficient peak has a blueshift. The strong BEF causes a redshift of the absorption coefficient peak and causes the absorption peak intensity to decrease remarkably. The physical reasons for these relationships have been analyzed in depth. 相似文献
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Konstantinos Spyrou Matteo Calvaresi Evmorfia K. Diamanti Theodoros Tsoufis Dimitrios Gournis Petra Rudolf Francesco Zerbetto 《Advanced functional materials》2015,25(2):263-269
Experimental and theoretical studies are performed in order to illuminate, for first time, the intercalation mechanism of polycyclic aromatic molecules into graphite oxide. Two representative molecules of this family, aniline and naphthalene amine are investigated. After intercalation, aniline molecules prefer to covalently connect to the graphene oxide matrix via chemical grafting, while napthalene amine molecules bind with the graphene oxide surface through π–π interactions. The presence of intercalated aromatic molecules between the graphene oxide layers is demonstrated by X‐ray diffraction, while the type of interaction between graphene oxide and polycyclic organic molecules is elucidated by X‐ray photoelectron spectroscopy. Combined quantum mechanical and molecular mechanical calculations describe the intercalation mechanism and the aniline grafting, rationalizing the experimental data. The present work opens new perspectives for the interaction of various aromatic molecules with graphite oxide and the so‐called “intercalation chemistry”. 相似文献
28.
研究了受外场驱动的两个二能级系统分别与两个单模量子化光场相互作用模型中纠缠演化及转移问题。该工作主要是对外场驱动的Landau-Zener模型进行了研究,采用旋转波近似的方法,通过数值计算详细分析了二能级系统初始状态、能级间的耦合常数以及驱动外场的参数对子系统间纠缠和转移特性的影响。结果表明,适当调节模型中的参数,可以使系统初始纠缠完全转移为光腔场间的纠缠,实现二能级系统与光场间的最大纠缠转移。 相似文献
29.
Private information retrieval(PIR) is an important privacy protection issue of secure multi-party computation, but the PIR protocols based on classical cryptography are vulnerable because of new technologies,such as quantum computing and cloud computing. The quantum private queries(QPQ) protocols available, however, has a high complexity and is inefficient in the face of large database. This paper, based on the QKD technology which is mature now, proposes a novel QPQ protocol utilizing the key dilution and auxiliary parameter. Only N quits are required to be sent in the quantum channel to generate the raw key, then the straight k bits in the raw key are added bitwise to dilute the raw key, and a final key is consequently obtained to encrypt the database. By flexible adjusting of auxiliary parameters θ and k, privacy is secured and the query success ratio is improved. Feasibility and performance analyses indicate that the protocol has a high success ratio in first-trial query and is easy to implement, and that the communication complexity of O(N) is achieved. 相似文献
30.
针对具有应用价值的卤代乙酸胍(GXA)非线性光学(NLO)晶体研究不系统的问题,设计了系列三卤代和系列氯代的乙酸胍(GAc)体系,通过量子化学计算研究了系列GXA的结构、NLO性质和构效关系,探讨了卤代效应可能的影响机理。结果表明,卤代原子显著地改变了GXA分子构象,并通过不同方式参与强氢键作用来影响超分子堆积。卤代主要通过影响GXA分子的LUMO来改变其能隙(Egap)。GXA的平均偶极矩(μtotal)和平均极化率<α>随卤原子数量以及半径的增大而增大。超极化率总体上相对于GAc降低,但影响复杂,其中,平均第1超极化率(βtotal)随卤原子数量的增多而降低,平均第2超极化率(<γ>)则随卤原子的变大而显著增强。此外,并未发现Egap与μtotal及<γ>之间存在明显的相关性。 相似文献